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Gold in the seawater of Precambrian oceans: application to Au deposits formation

Abstract

Oceanic carbonaceous deposits adsorb gold from seawater during sedimentation and diagenesis, and Au has formed part of sedimentary pyrite starting from 3.5 Ga. Water of the Meso- and Neoarchean oceans contained several times more Au than modern oceans. Au grade in the water of the oceans decreased, particularly after a global oxidative event in the Paleoproterozoic, and then slowly increased again in the Neoproterozoic (from 800 to 520 Ma). In the Archean  and Proterozoic, the Au grade in the seawater is correlated with the time of the distribution of high-Mg
basalts, komatiites and black shales in greenstone belts. Oxygen increase in the Earth’s atmosphere is combined with a low Au background in komatiites and Mg basalts, which previously enriched the seawater with gold. This is also indicated by the absence or insignificant amount of gold deposits in the period of 1600–800 Ma, which can be explained by low Au grade in the water of the oceans
during this age period.

About the Author

S. I. Turchenko
RAS Institute of the Precambrian Geology and Geochronology (IPGG RAS)
Russian Federation

Chief Researcher, Doctor of Geological and Mineralogical Sciences



References

1. Bushmin S. A., Belyatskiy B. V., Krymskiy R. Sh., Glebovitskiy V. A., Buyko A. K., Savva E. V., Sergeev

2. S. A. The isochronous Re-Os age of gold in the gold-quartz gold deposit Mayskoye (North Karelia, Baltic Shield). Doklady Rossijskoj Akademii Nauk. 2013. Vol. 448. No. 1, pp. 76–79. (In Russian).

3. Vrevskiy A. B. Petrologiya i geodinamicheskie rezhimy razvitiya arkheyskoy litosfery (na primere Baltiyskogo shchita) [Petrology and geodynamic regimes of the development of the Archean lithosphere (on the example of the Baltic Shield)]. Leningrad. 1989. 143 p.

4. Nekrasov I. I. Geokhimiya, mineralogiya i genezis mestorozhdeniy zolota [Geochemistry, mineralogy and genesis of gold deposits]. Moscow. 1996. 344 p.

5. Turchenko S. I., Gorokhovskiy B. M. Poligennaya priroda zolotorudnogo mestorozhdeniya Mayskoe (Cevernaya Kareliya): geologicheskie i izotopnye svidetel’stva. Region. geologiya i metallogeniya. 2018. No. 74, pp. 43–48. (In Russian).

6. Cherkasov G. A. Geochemistry of metal-bearing sediments in ore formation areas in the ocean. Hydrothermal sulfide ores and metal-bearing sediments in the ocean. Eds. by I. S. Gramberg, A. I. Aynemer. St. Petersburg. 1992. Pp. 138–142. (In Russian).

7. Chibisov N. A. Gold migration in the waters of rivers draining the Kolyma-Indigirka region. Geology and minerals of the Yakut Autonomous Soviet Socialist Republic. 1964. Vol. 6, pp. 112–128. (In Russian).

8. Anbar, A. D., Duan, Y., Lyons, T. W. et al. 2007: A whiff of oxygen before the great oxidation event? Science. 317. 1903–1906.

9. Canfield, D. E., Poulton, S. W., Knol, A. H. et al. 2008: Ferruginous conditions dominated later Neoproterozoic deep-water chemistry. Science. 321. 949–952.

10. Gregory, D. D., Meffre, S., Large, R. R. 2014: Comparison of metal enrichment in pyrite framboids

11. from a metal-enriched and metal-poor Estuary. American Mineralogist. 99. 633–644.

12. Gregory, D. D., Large, R. R., Halpin, J. A. et al. 2015: The chemical conditions of the late Archean

13. Hamersley basin inferred from whole rock and pyrite geochemistry with δ33S and δ34S isotope analyses. Geochimica et Cosmochimica Acta. 149. 223–250.

14. Guy, B. M., Beukes, N. J., Gutzmer, J. 2010: Paleoenvironmental controls on the texture and chemical composition of pyrite from non-conglomeratic sedimentary rocks of the Mesoarchean Witwatersrand Supergroup. South Africa. South African Journal of Geology. 113. 195–228.

15. Elderfield, H., Schultz, A. 1996: Mid-ocean ridge hydrothermal fluxes and the chemical composition of the ocean. Earth and Planetary Science Letters. 24. 191–224.

16. Hannington, M. D., de Ronde, C. D., Petersen, S. 2005: Sea-floor tectonics and submarine hydrothermal systems. Economic Geology. 100. 11–141.

17. Huerta-Diaz, M. A., Morse, J. W. 1992: Pyritization of trace metals in anoxic marine sediments.

18. Geochimica et Cosmochimica Acta. 56. 2681–2702.

19. Falkner, K. K., Edmond, J. M. 1992: Gold in seawater. Earth and Planetary Science Letters. 98. 208–221.

20. Johnson, K. S. Chemical Sensor Group. The Monterey Bay Aquarium Research Institute (MBARI): [Website]. URL: http://www.mbari.org/chemsensor/summary.html (8.04.2019).

21. Keays, R. R., Scott, R. B. 1976: Precious metals in ocean-ridge basalts; implications for basalts as source rocks for gold mineralization. Economic Geology. 71. 705–720.

22. Krauskopf, K. B. 1951: The solubility of gold. Economic Geology. 46. 858–870.

23. Large, R. R., Maslennikov, V. V., Robert, F. et al. 2007: Multistage sedimentary and metamorphic

24. origin of pyrite and gold in the Giant Sukhoi Log deposit, Lena Gold Province, Russia. Economic Geology. 102. 1233–1267.

25. Large, R. R., Halpin, J. A., Danyushevsky, L. V. et al. 2014: Trace element content of sedimentary pyrite as a new proxy for deep-time ocean-atmosphere evolution. Earth and Planetary Science Letters. 389. 209–220.

26. Pitcairn, I. K., Teagle, D. A. H., Craw, D. et al. 2006: Sources of metals and fluids in orogenic gold

27. deposits: insights from the Otago and Alpine schists, New Zealand. Economic Geology. 101. 1525–1546.

28. Planavsky, N. J., McGoldrick, P., Scott, C. T. et al. 2011: Widespread iron-rich conditions in the mid-

29. Proterozoic ocean. Nature. 477. 448–451.

30. Smirnov, A. V., Evans, D. A. D., Ernst, R. E. et al. 2013: Trading partners: tectonic ancestry of southern

31. Africa and western Australia, in Archean supercratons Vaalbara and Zimgarn. Precambrian Research. 224. 1–22.

32. Tomkins, A. G. 2013: A biogeochemical influence on the secular distribution of orogenic gold. Economic Geology. 108. 193–197.

33. Vlassopoulos, D., Wood, S. A. 1990: Gold speciation in natural waters: I. Solubility and hydrolysis

34. reactions of gold in aqueous solution Geochimica et Cosmochimica Acta. 54. 3–12.


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Turchenko S.I. Gold in the seawater of Precambrian oceans: application to Au deposits formation. Regional Geology and Metallogeny. 2019;(78):76–81. (In Russ.)

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