Ryabinovoe copper-gold-porphyry deposit (Southern Yakutia): geology, noble gases isotope systematics and isotopic (U-Pb, Rb-Sr, Re-Os) dating of wallrock alteration and ore-forming processes
Abstract
In the Ryabinovoe copper-gold-porphyry deposit, the ore mineralization is belonging to multi-stage metasomatism fields, which were formed in two stages. In the first, pre-ore stage, high-temperature potassium-sodium metasomatites – aegirine feldspathites – were appeared whereas gumbeites – in the second, low/medium-temperature stage as a both – carbonate-sericite-muscovite-orthoclase and quartz-carbonate-barite-adular varieties. The results of isotopic investigations (U-Pb, Rb-Sr, Re-Os, 40Ar/36Ar, 3He/4He, 20Ne) of the above-mentioned metasomatites and ore mineralization are discussed in the paper.
About the Authors
N. V. ShatovaRussian Federation
Leading Engineer
A. V. Molchanov
Russian Federation
Doctor of Geological and Mineralogical Sciences, Head of Department
A. V. Terekhov
Russian Federation
Candidate of Geological and Mineralogical Sciences, Deputy head of the Department
V. V. Shatov
Russian Federation
Candidate of Geological and Mineralogical Sciences, Deputy General Director
O. V. Petrov
Russian Federation
Doctor of Geological and Mineralogical Sciences, Doctor Economic Sciences, Director General
S. A. Sergeev
Russian Federation
Candidate of Geological and Mineralogical Sciences, Director, Center for Isotopic Research
Eh. M. Prasolov
Russian Federation
Doctor of Geological and Mineralogical Sciences, Leading Scientist
G. P. Dvornik
Russian Federation
Doctor of Geological and Mineralogical Sciences, Leading Scientist
V. I. Leontev
Russian Federation
Candidate of Geological and Mineralogical Sciences, Associate Professor; Leading Geologist
References
1. Baskov E. A. Paleogidrogeologicheskij analiz pri metallogenicheskih issledovaniyah [Palaeohydrogeological analysis in the metallogenic investigations]. Leningrad: Nedra. 1976. 199 p.
2. Boitsov V. E., Pilipenko G. N., Dorozhkina L. А. Gold and gold-uranium ore deposits of the Central Aldan region. Large and giant ore deposits in 3 volumes. Vol. 2: Strategical types of ore minerals. Moscow: IGEM RAS. 2006. P. 215–240. (In Russian).
3. Vetluzhskikh V. G., Kazansky V. I., Kochetkov A. Ya., Yanovsky V. M. Gold ore deposits of the Central Aldan region. Geologiya rudnyh mestorozhdenij. 2002. Vol. 44. No 6, pp. 467–499. (In Russian).
4. Grabezhev A. I., Belgorodsky E. A. Produktivnyye granitoidy i metasomatity medno-porfirovykh mestorozhdeniy (na primere Urala) [Productive granitoids and metasomatites of porphyry copper deposits (using the example of the Urals)]. Yekaterinburg: Nauka. 1992. 199 p.
5. Dvornik G. P. Sericite-microcline metasomatites and gold mineralization of the Ryabinovoe ore field (Aldan Shield). Litosfera. 2009. No 2, pp. 56–66. (In Russian).
6. Dvornik G. P. Gold and silver distribution in orebodies of the Ryabinovoe and Novoe deposits (the Aldan Shield). Litosfera. 2011. No 4, pp. 119–130. (In Russian).
7. Dvornik G. P. Metasomatizm i zolotoe orudenenie kalievyh shchelochnyh massivov (na primere Central’no-Aldanskoj shchelochnoj provincii) [Metasomatites and gold mineralization of high potassium alkaline massifs (by example from the Central Aldan alkaline province)]. Yekaterinburg. 2014. 329 p.
8. Zagruzina I. A., Golubchina M. N., Kochetkov A. Ya. i dr. Sulfur isotopic composition of sulphide minerals from the alkaline massif, Central Aldan region. DAN SSSR. 1983. Vol. 271. No 2, pp. 405–407. (In Russian).
9. Zharikov V. A., Rusinov V. L., Marakushev А. А., Zaraisky G. P., Omelyanenko B. I. i dr. Metasomatizm i metasomaticheskie porody [Metasomatism and metasomatic rocks]. Мoscow: Nauchy mir. 1998. 492 p.
10. Kazitsyn Yu. V. Metasomatizm gidrotermal’nyh mestorozhdenij [Metasomatism of hydrothermal ore deposits]. Leningrad: Neda. 1972. 145 p.
11. Kim А. А. Mineralogical and geochemical ore mineralization patterns related to the alkaline massif, Central Aldan region. Mineralogical and geochemical patterns of ore deposits of the Eastern and Southern Yakutia. Yakutsk. 1981. P. 93–108. (In Russian).
12. Kislyi A. V., Sotnikov O. V., Utkina N. E. i dr. Otchet o rezul’tatah perescheta zapasov zolotorudnogo mestorozhdeniya Ryabinovoe v Aldanskom rajone Respubliki Saha (Yakutiya) po sostoyaniyu na 01.06.2011. Kn. 1 [Report on the results of reserves assessment of the Ryabinovoe gold deposit, Aldan region, Yakutia as 01.06.2011]. Vol. 1. St. Petrsburg. 2011. 250 p.
13. Kovalenker V. A., Myznikov I. K., Kochetkov A. Ya., Naumov V. B. PGE-bearing gold-sulphide mineralization in the Ryabinovy alkaline massif (Central Aldan, Russia). Geologiya rudnyh mestorozhdenij. 1996. Vol. 38. No 4, pp. 345–356. (In Russian).
14. Korzhinsky D. S. Petrology of the Tur’insk copper skarn deposits. Proceedings of the Institute of Internal Sciences of the USSR, iss. 68. Мoscow. 1948. 148 p. (In Russian).
15. Kochetkov A. Ya. On new type of copper-porphyry mineralization. DAN SSSR. 1982. Vol. 267. No 2, pp. 430–432. (In Russian).
16. Kochetkov A. Ya. Porphyry copper-ore mineralization of zones of Mesozoic tectonic-magmatic activation of the Aldan Shield. Siberian Tectonics. Vol. 12: Tectonics of the activated regions. Novosibirsk: Nauka. 1983. P. 130–140. (In Russian).
17. Kochetkov A. Ya. The Ryabinovoe Mo-Cu-Au-porphyry deposit. Otechestvennaya geologiya. 1993. No 7, pp. 50–58. (In Russian).
18. Kochetkov A. Ya. Mineral potential of alkaline massifs of the Aldan Shield. The Ryabinovoe copper-gold-porphyry deposit. Tikhookeanskaya geologiya. 2006. Vol. 25. No 1, pp. 62–73. (In Russian).
19. Kochetkov A. Ya., Pakhomov V. N., Popov A. B. Magmatism and metasomatism of the Ryabinovy alkaline orebearingmassif (Central Aldan). Magmatism of copper-molybdenum ore knots. Novosibirsk: Nauka. 1989. Pp. 79–110. (In Russian).
20. Krivtsov A. I., Zvezdov V. S., Migachev I. F., Minina O. V. Medno-porfirovye mestorozhdeniya. Seriya: Modelimestorozhdenij blagorodnyh i cvetnyh metallov [Copper-porphyry deposits. Part: Models of precious and base metals]. Мoscow: TSNIGRI. 2001. 232 p.
21. Lukashenko S. V., Pilipenko G. N. New geological and commercial type of gold-porphyry deposits (by example of the Ryabinovoe deposit). Razvedka i okhrana nedr. 2012. No 2. P. 35–38. (In Russian).
22. Marin Yu. B. Granitoidnye formacii malyh i umerennyh glubin [Granitoid complexes of near-surface and moderate depths of generation]. Leningrad. 1976. 143 p.
23. Molchanov A. V., Shatov V. V., Terekhov А. V., Belova V. N., Rad’kov А. V., Semenova V. V., Soloviev O. L., Shatova N. V. The Elkon gold and uranium ore knot (South Yakutia): Main features of geological setting, petrography and mineralogy of alteration types and mineral potential. Region. geologiya
24. i metallogeniya. 2012. No 50, pp. 80–101. (In Russian).
25. Pavlova I. G. Medno-porfirovye mestorozhdeniya (Zakonomernosti razmeshcheniya i kriterii prognozirovaniya) [Copper-porphyry deposits: Distribution patterns and criteria of prognostic assessment]. Leningrad: Nedra. 1978. 275 p.
26. Popov V. S. Geologiya i genezis medno- i molibdenporfirovyh mestorozhdenij [Geology and genesis of copper- and molybdenum-porphyry deposits]. Мoscow: Nauka. 1977. 204 p.
27. Prasolov Eh. M. Izotopnaya geohimiya i proiskhozhdenie prirodnyh gazov [Isotopic geochemistry and origin of natural gases]. Leningrad: Nedra. 1990. 280 p.
28. Soloviev S . G. Metallogeniya shoshonitovogo magmatizma(v dvuh tomah). Tom 1 [Metallogeny of shoshonitic magmatism (in two volumes). Vol. 1]. Мoscow: Nauchnyi mir. 2014. 528 p.
29. Sotnikov V. I., Polyvyannyi E. I., Proskuryakov A. A. On participation of vadose waters in formation of the Sora porphyry deposit. Geologiya i geofizika. 1973. No 2, pp. 124–128. (In Russian).
30. Terekhov A. V., Molchanov A. V., Shatova N. V., Belova V. N. Two types of ore-bearing gumbeitic alteration from the Elkon gold and uranium ore knot (South Yakutia). Region. geologiya i metallogeniya. 2014. No 60, pp. 71–86. (In Russian).
31. Ugryumov A. N., Dvornik G. P. Ore-bearing alkaline metasomatites of the Ryabinovy massif (Aldan Shield). Sovetskaya geologiya. 1984. No 9, pp. 84–94. (In Russian).
32. Shatov V. V., Molchanov A. V., Shatova N. V., Sergeev S. A., Belova V. N., Terekhov A. V., Rad’kov A. V., Soloviev O. L. Petrography, geochemistry and isotopic (U-Pb and Rb‑Sr) dating of alkaline magmatic rocks of the Ryabinovy massif (South Yakutia). Region. geologiya i metallogeniya. 2012. No 51, pp. 62–78. (In Russian).
33. Shatova N. V. Petrography and geochemistry of alkaline intrusive rocks of the Ryabinovy massif (South Yakutia). Materials of the II International Scientific-Practical. Conferences of young scientists and specialists in memory of Academician A. P. Karpinsky (February 8–11, 2011). St. Petersburg: VSEGEI. 2011. Pp. 343–347. (In Russian).
34. Shatova N. V. Geochemistry and petrography of hydrothermally altered rocks of the Ryabinovoe ore field (South Yakutia) and forecasting Au-Cu-porphyry ore mineralization. Materials of the IV International Scientific-Practical. Conferences of young scientists and specialists in memory of Academician A. P. Karpinsky (February 16–20, 2015). St. Petersburg: VSEGEI. 2015. P. 302–305. (In Russian).
35. Shatova N. V., Skublov S. G., Melnik A. E., Shatov V. V., Molchanov A. V., Terekhov A. V., Sergeev S. A.
36. Geochronology of alkaline magmatic rocks and metasomatites of the Ryabinovy stock (South Yakutia) based on zircon isotopic and geochemical (U-Pb, REE) investigations. Region. geologiya i metallogeniya. 2017. No 69, pp. 33–48. (In Russian).
37. Shcherban’ I. P. Usloviya obrazovaniya nizkotemperaturnyh okolorudnyh metasomatitov (na primere Altae-Sayanskoj oblasti) [Condition formation of low temperature wallrock alterations (by example of the Altai-Sayan fold area)]. Novosibirsk: Nauka. 1975. 200 p.
38. Bath, A. B., Cooke, D. R., Friedman, R. M., Faure, K., Kamenetsky, V. S., Tosdal, R. M., Berry, R. F. 2014: Mineralization, U-Pb geochronology, and stable isotope geochemistry of the Lower Main Zone of the Lorraine deposit, North-Central British Columbia: A replacement-style alkalic Cu-Au porphyry.
39. Econ. Geology. 109. 979–1004.
40. Byrne, K., Tosdal, R. M. 2014: Genesis of the Late Triassic Southwest zone breccia-hosted alkalic porphyry Cu-Au deposit, Galore Creek, British Columbia, Canada. Econ. Geology. 109. 915–938.
41. Cathles, L. M. 1977: An analysis of the cooling of intrusives by ground-water convection which includes boiling. Econ. Geology. 72. 804–826.
42. Devine, F. A. M., Chamberlain, C. M., Davies, A. G .S., Friedman, R., Baxter, P. 2014: Geology and district-scale setting of Tilted alkalic porphyry Cu-Au mineralization at the Lorraine deposit, British Columbia. Econ. Geology. 109. 939–977.
43. Lowell, J. D., Guilbert, J. M. 1970: Lateral and vertical alteration-mineralization zoning in porphyry ore deposits. Econ. Geology. 65. 4. 373–408.
44. Muller, D., Groves, D. I. 2016: Potassic igneous rocks and associated gold-copper mineralization. Mineral Resource Reviews. Heidelberg: Springer-Verlag. 311.
45. Norton, D., Knight, J. 1977: Transport phenomena in hydrothermal systems: Cooling plutons. American Journal of Science. 277. 937–981.
46. Sheppard, S. M. F., Nielsen, R. L., Taylor, H. P., Jr. 1971: Hydrogen and oxygen isotope ratios in minerals from porphyry copper deposits. Econ. Geology. 66. 4. 515–542.
47. Sheppard, S. M. F., Taylor, H. P., Jr. 1974: Hydrogen and oxygen isotope evidence for the origins of water in the Boulder batholith and the Butte ore deposits, Montana. Econ. Geology. 69. 6. 926–946.
48. Sillitoe, R. H. 2010: Porphyry copper systems. Econ. Geology. 105. 1. 3–41.
49. Sinclair, W. D. 2007: Porphyry deposits. In Goodfellow, W. D. (ed.): Mineral deposits of Canada: A synthesis of major deposit-types, district metallogeny, the evolution of geological provinces,
50. and exploration methods: Geological Association of Canada, Mineral Deposits Division, Special Publication. 5. 223–243.
51. Taylor, H. P., Jr. 1971: Oxygen isotope evidence for large-scale interaction between meteoric ground waters and Tertiary granodiorite intrusions, Western Cascada Range, Oregon. Journal of Geophysical Research. 76. 32. 7855–7874.
52. Taylor, H. P., Jr. 1973: O18/O16 evidence for meteorichydrothermal alteration and ore deposition in the Tonopah, Comstock Lode, and Goldfield Mining Districts, Nevada. Econ. Geology. 68. 6. 747–764.
53. Taylor, H. P., Jr. 1974: The application of oxygen and hydrogen isotope studies to problems of hydrothermal alteration and ore deposition. Econ. Geology. 69. 6. 843–883.
54. Wolfe, R. C., Cooke, D. R. 2011: Geology of the Didipio region and genesis of the Dinkidi alkalic porphyry Cu-Au deposit and related pegmatites, Northern Luzon, Philippines. Econ. Geology. 106. 8. 1279–1315.
Review
For citations:
Shatova N.V., Molchanov A.V., Terekhov A.V., Shatov V.V., Petrov O.V., Sergeev S.A., Prasolov E.M., Dvornik G.P., Leontev V.I. Ryabinovoe copper-gold-porphyry deposit (Southern Yakutia): geology, noble gases isotope systematics and isotopic (U-Pb, Rb-Sr, Re-Os) dating of wallrock alteration and ore-forming processes. Regional Geology and Metallogeny. 2019;(77):75–97. (In Russ.)