Preview

Regional Geology and Metallogeny

Advanced search

Reductive decomposition: A basis for the universal technique of analyzing rocks for noble metals content

https://doi.org/10.52349/08697892_2021_85_93_102

Abstract

The paper describes a new technique for analyzing rocks of various compositions for the content of noble metals, such as Au, Pt, Pd, Rh, Ru, Ir, by inductively coupled plasma mass spectrometry, the main feature of which is the abandonment of acids – oxidizers, which are used in sample decomposition. Results of domestic and international comparison tests, which show that in the overwhelming majority of cases the new technique has undeniable advantages over the traditionally used ones, including with assay melting are provided.

About the Authors

G. A. Oleynikova
A. P. Karpinsky Russian Geological Research Institute (VSEGEI)
Russian Federation

Candidate of Chemical Sciences, Chief, Central Laboratory



Yu. N. Borin
A. P. Karpinsky Russian Geological Research Institute (VSEGEI)
Russian Federation

Head of Sector, Central Laboratory



V. L. Kudryashov
A. P. Karpinsky Russian Geological Research Institute (VSEGEI)
Russian Federation

Head of Laboratory, Central Laboratory



V. A. Shishlov
A. P. Karpinsky Russian Geological Research Institute (VSEGEI)
Russian Federation

Leading Engineer, Central Laboratory



S. S. Shevchenko
A. P. Karpinsky Russian Geological Research Institute (VSEGEI)
Russian Federation

Candidate of Geological and Mineralogical Sciences, Deputy General Director



O. V. Petrov
A. P. Karpinsky Russian Geological Research Institute (VSEGEI)
Russian Federation

Corresponding Member of RAS, Doctor of Geological and Mineralogical Sciences, Doctor Economic Sciences, Director General



References

1. Analiz mineral’nogo syr’ya [Analysis of mineral raw materials]. Ed. by Yu. N. Knipovich, Yu. V. Morachevsky. Izd. vtoroe, pererabotannoe i dopolnennoe. Leningrad, Lengoskhimizdat, 1956, 1055 p.

2. Analiticheskaya khimiya metallov platinovoy gruppy: Sbornik obzornykh statey [Analytical chemistry of platinum group metals: Collection of review articles]. Compilers and editors: Yu. A. Zolotov, G. M. Varshal, V. M. Ivanov. Izd. 2-e, stereotipnoe. Moscow, 2005, 592 p.

3. Vnutrenniy laboratornyy kontrol’ tochnosti (pravil’nosti i pretsizionnosti) rezul’tatov kolichestvennogo khimicheskogo analiza [Internal laboratory control of the accuracy (correctness and precision) of the results of quantitative chemical analysis]. Upravlenie kachestvom analiticheskikh rabot: OST 41-08-214-04. UKAR. Introduced 2005.09.01. Moscow, 2004, 92 p.

4. Danilova F. I., Fedotova I. A., Nazarenko R. M. Probirno-khimiko-spektral’noe opredelenie metallov gruppy platiny i zolota v sul’fidnykh medno-nikelevykh rudakh i produktakh ikh pererabotki [Assay-chemical-spectral determination of metals of the platinum and gold group in sulfide copper-nickel ores and products of their processing]. Zavodskaya laboratoriya, 1982, vol. 48, no. 8, pp. 9–10. (In Russian).

5. Smirnova S. V., Pletnev I. V. New ionic liquids for extraction preconcentration. Journal of Analytical Chemistry, 2019, vol. 74, no. 1, pp. 3. (In Russian).

6. Lobanov V. G., Radionov B. K., Skorokhodov V. I., Goryaeva O. Yu., Lobanova S. A., Pritchin A. A. Sposob izvlecheniya blagorodnykh metallov iz rastvora sorbtsiey [Method for extracting noble metals from solution by sorption]. Patent 2267544 Rossiyskaya Federatsiya no. 2004123277/02 (2006).

7. Smetannikov A. F., Serebryanyy B. L., Krasnoshteyn A. E. Sposob kachestvennogo i kolichestvennogo opredeleniya organicheskikh soedineniy blagorodnykh metallov v porodakh razlichnogo sostava [Method for the qualitative and quantitative determination of organic compounds of noble metals in rocks of various composition]. Patent 2354967 Rossiyskaya Federatsiya no. 2007134762/28 2 (2009).

8. Bazhov A. S., Sokolova E. A. Sposob opredeleniya zolota [Method for determining gold]. Avtorskoe svidetel’stvo 880985 Soyuz Sovetskikh Sotsialisticheskikh Respublik no. 2843784 (1981).

9. Mirgorod Yu. A., Anikin V. Yu., Bychikhin A. S. Sposob opredeleniya soderzhaniya palladiya i platiny v rudakh [Method for determining the content of palladium and platinum in ores]. Patent 2283356 Rossiyskaya Federatsiya no. 2005100165/02 (2006).

10. Oleynikova G. A., Serbina M. N., Reutova I. V. Sposob opredeleniya kolichestvennogo soderzhaniya blagorodnykh metallov v gornykh porodakh i otvalakh gornorudnogo proizvodstva [Procedure for determination of quantitative contents of valuable metals in rock and piles of metal mining production]. Patent 2425363 Rossiyskaya Federatsiya no. 2010119745/15 (2011).

11. Serebryanyy B. L., Makarov Yu. B., Simakova L. G., Chekashkina L. V., Mandrugin A. V. Sposob probirnogo opredeleniya zolota v rudakh i produktakh ikh pererabotki [Method for assay determination of gold in ores and products of their processing]. Patent RU 2 288 288 Rossiyskaya Federatsiya no. 2005115829/02 (2006).

12. Asano S., Kheguri S., Manabe Y., Kasai M., Kurokava Kh. Sposob sovmestnogo otdeleniya metallov platinovoy gruppy [Method of joint separation of platinum group metals]. Patent 2004128063 Rossiyskaya Federatsiya no. 2004128063/02 (2009).

13. Afenia P. Treatment of Refractory Gold Ores. Minerals Engineering, 1991, vol. 4, pр. 1043.

14. Albert R., Horwitz W. The amazing Horwitz Function. Journal of Analytical Chemistry, 1997, vol. 69, pp. 789.


Review

For citations:


Oleynikova G.A., Borin Yu.N., Kudryashov V.L., Shishlov V.A., Shevchenko S.S., Petrov O.V. Reductive decomposition: A basis for the universal technique of analyzing rocks for noble metals content. Regional Geology and Metallogeny. 2021;(85):93–102. (In Russ.) https://doi.org/10.52349/08697892_2021_85_93_102

Views: 4


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 0869-7892 (Print)